Table 2.
Adsorption kinetics parameters of toluene and p-xylene adsorption.
| Model | Parameters | Toluene | p-xylene | ||
|---|---|---|---|---|---|
| Pure CNTs | CNTs-iron oxide | Pure CNTs | CNTs-iron oxide | ||
| C o | 60.70 | 60.70 | 47.78 | 47.78 | |
|
| |||||
| Experimental | q e,experimental | 76.04 | 79.87 | 81 | 79.11 |
|
| |||||
| Pseudo-first-order | k 1(min−1)∗10−3 | 5.3 | 3.1 | 4.7 | 4.2 |
| q e,calculated | 7.43 | 6.94 | 4.92 | 5.10 | |
| R 2 (%) | 95 | 80 | 97 | 97 | |
|
| |||||
| Pseudo-second-order | k 2 (g mg−1 min−1)∗10−4 | 0.69 | 0.32 | 3.9 | 3.1 |
| q e,calculated | 107.53 | 128.21 | 87.72 | 86.96 | |
| R 2 (%) | 98 | 80 | 99.9 | 99.7 | |
|
| |||||
| Intraparticle diffusion model | k id (g mg−1 min−0.5) | 4.04 | 4.51 | 1.96 | 1.97 |
| C | 4.74 | −6.99 | 46.66 | 43.23 | |
| R 2 (%) | 91 | 93 | 85 | 96 | |