Table 3.
Mycotoxin | Precursor ion | Q1 (m/z) | Q3 (m/z) | Time (msec) | DP (volts) | EP (volts) | CE (volts) | CXP (volts) |
---|---|---|---|---|---|---|---|---|
NIV | [M + CH3COO−]− | 313 313 |
175 295 |
100 100 |
41 41 |
5 5 |
19 15 |
6 6 |
DON | [M + CH3COO−]− | 297.2 297.2 |
249.2 231.2 |
100 100 |
40 40 |
7.5 7.5 |
12 12 |
4 4 |
3-AcDON | [M + CH3COO−]− | 339 339 |
231 213 |
100 100 |
15 15 |
3.5 3.5 |
15 15 |
2 2 |
AFB1 | [M + H]+ | 313 313 |
285.1 115 |
100 100 |
70 70 |
11 11 |
51 89 |
4 4 |
AFB2 | [M + H]+ | 313 313 |
287.1 259.1 |
100 100 |
70 70 |
10 10 |
50 50 |
3 3 |
AFG1 | [M + H]+ | 329 329 |
243.0 215.1 |
100 100 |
70 70 |
11 10 |
25 50 |
4 4 |
AFG2 | [M + H]+ | 331 331 |
189 257 |
100 100 |
70 70 |
10.0 10.5 |
50 47 |
3 4 |
FB1 | [M + H]+ | 722.4 722.4 |
334.3 352.4 |
100 100 |
91 91 |
8 8 |
53 43 |
6 6 |
FB2 | [M + H]+ | 706.4 706.4 |
336.4 318.2 |
100 100 |
70 70 |
9 9 |
45 47 |
6 6 |
HT-2 | [M + NH4]+ | 442 442 |
263 215 |
100 100 |
26 26 |
3 3 |
19 19 |
4 4 |
T-2 | [M + NH4]+ | 484.1 484.1 |
215.2 185.2 |
100 100 |
21 21 |
6 6 |
29 31 |
4 4 |
ZEN | [M − H]− | 317.1 317.1 |
131 175 |
100 100 |
−50 −50 |
−4.5 −4.5 |
−40 −34 |
−2 −2 |
OTA | [M + H]+ | 404 404 |
239 220.9 |
100 100 |
41 41 |
5 5 |
31 19 |
4 4 |