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. 2017 Mar 23;2(3):1146–1155. doi: 10.1021/acsomega.7b00078

Table 2. Estragole Isomerization in Biphasic Systems Containing ILs and Charge-Tagged Ligandsa.

entry ligand conversion (%) selectivity (%)b Ru content (mg/kg)c
1   100 96 160 ± 4
first recharge 39 82  
second recharge 7 86  
2 L1 100 96 61.1 ± 2.1
first recharge 88 77  
second recharge 17 82  
a

Reaction conditions: estragole 13.0 mmol, estragole/1 = 2500, BMI·PF6 0.5 g, t = 20 min and 1 h, T = 80 °C, estragole filtered over aluminum oxide, and products separated by decantation.

b

Selectivity for trans-anethole.

c

Ru content in the organic phase.