Table 2. Estragole Isomerization in Biphasic Systems Containing ILs and Charge-Tagged Ligandsa.
| entry | ligand | conversion (%) | selectivity (%)b | Ru content (mg/kg)c |
|---|---|---|---|---|
| 1 | 100 | 96 | 160 ± 4 | |
| first recharge | 39 | 82 | ||
| second recharge | 7 | 86 | ||
| 2 | L1 | 100 | 96 | 61.1 ± 2.1 |
| first recharge | 88 | 77 | ||
| second recharge | 17 | 82 |
Reaction conditions: estragole 13.0 mmol, estragole/1 = 2500, BMI·PF6 0.5 g, t = 20 min and 1 h, T = 80 °C, estragole filtered over aluminum oxide, and products separated by decantation.
Selectivity for trans-anethole.
Ru content in the organic phase.