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. 2017 Feb 2;121(12):6626–6634. doi: 10.1021/acs.jpcc.6b12097

Scheme 1. Reversible Exchange of para-H2 and Substrate on the Polarization Transfer Catalyst Leads to Continuous Buildup of Polarization on the Free Substrate.

Scheme 1

The J-couplings in the polarization transfer complex drive the polarization transfer. L: Ligands. Rx: arbitrary group.