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. 2017 Apr 3;375(2093):20160161. doi: 10.1098/rsta.2016.0161

Figure 2.

Figure 2.

We model the directional solidification of a drying colloidal dispersion, in one dimension. The colloidal dispersion enters from a reservoir on the far left, at some volume fraction ϕ=ϕ0 and evaporation occurs at the far right at a rate Inline graphic. A solid deposit grows in from the drying edge at a velocity w. Near the liquid–solid transition the particles slow down, from an initial velocity Inline graphic to zero, and concentrate until they reach a final volume fraction ϕf. This results in a thin transition region, governed by a balance between advection and diffusion, where the properties of the dispersion change rapidly. This drying front grows into the cell, at velocity w, along with the solid deposit.