Table 2. Internal quantum efficiency (ΦIQ), carrier formation efficiency (ΦCF), carrier transfer efficiency (ΦCT = ΦIQ/ΦCF), and fullerene mixing (ΦFullerene) within the polymer matrix of OSCs based on films of F8T2/PC71BM (33 : 67 wt%) blend annealed for 10 min at Tan. The error bars of ΦCF were roughly evaluated from the signal/noise ratio of the femtosecond time-resolved spectra. ΦFullerene was evaluated by least-squares fitting of the observed spectra (φexp) with the linear combination of the F8T2 (φD) and PC71BM (φA) spectra, φcal = CDφD + CAφA. The averages and standard deviations of CD and CA were evaluated from ten φexp spectra at every Tan. The ΦFullerene values were calculated by CA/(CD + CA).
Tan (°C) | ΦIQ @ 400 nm | ΦCF @ 400 nm | ΦCT @ 400 nm | CD | CA | ΦFullerene |
---|---|---|---|---|---|---|
40 | 0.368 ± 0.011 | 0.76 ± 0.04 | 0.48 ± 0.04 | 0.75 ± 0.07 | 0.47 ± 0.05 | 0.38 ± 0.08 |
80 | 0.342 ± 0.009 | 0.76 ± 0.04 | 0.45 ± 0.04 | 0.85 ± 0.05 | 0.36 ± 0.06 | 0.29 ± 0.08 |
110 | 0.336 ± 0.009 | 0.69 ± 0.04 | 0.49 ± 0.04 | 0.84 ± 0.04 | 0.36 ± 0.04 | 0.30 ± 0.05 |
150 | 0.285 ± 0.007 | 0.53 ± 0.04 | 0.53 ± 0.05 | 0.90 ± 0.07 | 0.33 ± 0.05 | 0.27 ± 0.07 |
190 | 0.300 ± 0.010 | 0.48 ± 0.04 | 0.63 ± 0.07 | 0.76 ± 0.03 | 0.31 ± 0.06 | 0.29 ± 0.09 |
240 | 0.310 ± 0.015 | 0.59 ± 0.04 | 0.53 ± 0.06 | -------- | -------- | -------- |