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. 2014 May 28;4:5086. doi: 10.1038/srep05086

Table 1. Influence of reaction solvent, temperature, and ratio of sulfur sources (dodecanethiol (Dod-SH) and sulfur element (S)) to the metal oleate precursor (Cu2ZnSn(C18H33O2)10) on the crystal phase and morphology of the CZTS nanocrystal products.

Shape of wurtzite structure Molar ratio of Dod-SH/Cu2ZnSn(C18H33O2)10
64 320 320    
Reaction temp. °C 250 Spherical in OLA + ODE Rod-like in ODE Rice-like in OA