Table 6. Detailed results for repeatability (DA), reproducibility (CO) and concordance odds ratio (COR) obtained during the collaborative study for the different methods.
Sample codes | Criteria | Results obtained for each method | ||||||
---|---|---|---|---|---|---|---|---|
M1 | M2 | Maa | M3 | M4 | M5 | M6 | ||
A1 | DAb | 0.94 | 1.00 | 0.94 | 0.94 | 0.90 | 1.00 | 1.00 |
COc | 0.68 | 0.40 | 0.20 | 0.68 | 0.76 | 1.00 | 1.00 | |
CORdf | 7.37 | inf | 62.67 | 7.37 | 2.84 | 1.00 | 1.00 | |
CICORef | 2.92–18.61 | - | 9.19–427.28 | 2.92–18.61 | 1.28–6.32 | - | - | |
Pfg | 0.002 S** | 0.000 S*** | 0.048 S* | 0.002 S** | 0.022 S* | 1.000 NS | 1.000 NS | |
A2 | DA | 0.90 | 1.00 | 0.94 | 0.90 | 0.94 | 1.00 | 1.00 |
CO | 0.84 | 0.40 | 0.80 | 0.84 | 0.92 | 1.00 | 1.00 | |
COR | 1.71 | inf | 3.92 | 1.71 | 1.36 | 1.00 | 1.00 | |
CICOR | 0.74–3.99 | - | 0.57–26.71 | 0.74–3.99 | 0.45–4.08 | - | - | |
p | 0.167 NS | 0.000 S*** | 1.000 NS | 0.167 NS | 1.000 NS | 1.000 NS | 1.000 NS | |
A3 | DA | 0.94 | 0.90 | 0.94 | 0.94 | 1.00 | 1.00 | 1.00 |
CO | 0.92 | 0.52 | 0.80 | 0.92 | 1.00 | 1.00 | 1.00 | |
COR | 1.36 | 8.31 | 3.92 | 1.36 | 1.00 | 1.00 | 1.00 | |
CICOR | 0.45–4.08 | 3.88–17.80 | 0.57–26.71 | 0.45–4.08 | -! | - | - | |
p | 1.000 NS | 0.000 S*** | 1.000 NS | 1.000 NS | 1.000 NS | 1.000 NS | 1.000 NS | |
A4 | DA | 0.65 | 0.84 | 0.87 | 0.94 | 0.90 | 1.00 | 0.94 |
CO | 0.51 | 0.70 | 0.68 | 0.68 | 0.84 | 1.00 | 0.92 | |
COR | 1.78 | 2.25 | 3.15 | 7.37 | 1.71 | 1.00 | 1.36 | |
CICOR | 1.01–3.15 | 1.13–4.46 | 0.75–13.25 | 2.92–18.61 | 0.74–3.99 | - | 0.45–4.08 | |
p | 0.290 NS | 0.081 NS | 1.000 NS | 0.002 S** | 0.167 NS | 1.000 NS | 1.000 NS | |
A5 | DA | 0.68 | 1.00 | 0.90 | 0.90 | 1.00 | 1.00 | 0.78 |
CO | 0.58 | 1.00 | 0.60 | 0.76 | 1.00 | 1.00 | 0.72 | |
COR | 1.54 | 1.00 | 6.00 | 2.84 | 1.00 | 1.00 | 1.38 | |
CICOR | 0.86–2.74 | - | 1.30–27.77 | 1.28–6.32 | - | - | 2.62 | |
p | 0.467 NS | 1.000 NS | 0.444 NS | 0.022 S* | 1.000 NS | 1.000 NS | 0.753 NS | |
B1 | DA | 0.90 | 0.94 | 0.94 | 0.94 | 0.81 | 1.00 | 1.00 |
CO | 0.84 | 0.40 | 0.80 | 0.92 | 0.65 | 1.00 | 1.00 | |
COR | 1.71 | 23.50 | 3.92 | 1.36 | 2.30 | 1.00 | 1.00 | |
CICOR | 0.74–3.99 | 9.39–58.80 | 0.57–26.71 | 0.45–4.08 | 1.20–4.38 | - | - | |
p | 0.167 NS | 0.000 S*** | 1.000 NS | 1.000 NS | 0.047 S* | 1.000 NS | 1.000 NS | |
B2 | DA | 0.94 | 0.94 | 0.87 | 0.84 | 1.00 | 1.00 | 0.90 |
CO | 0.92 | 0.44 | 0.68 | 0.78 | 1.00 | 1.00 | 0.84 | |
COR | 1.36 | 19.94 | 3.15 | 1.48 | 1.00 | 1.00 | 1.71 | |
CICOR | 0.45–4.08 | 7.99–49.78 | 0.75–13.25 | 0.73–3.02 | - | - | 0.74–3.99 | |
p | 1.000 NS | 0.000 S*** | 1.000 NS | 0.457 NS | 1.000 NS | 1.000 NS | 0.167 NS | |
B3 | DA | 0.58 | 0.90 | 0.90 | 0.90 | 0.87 | 0.90 | 0.68 |
CO | 0.48 | 0.48 | 0.40 | 0.76 | 0.85 | 0.84 | 0.58 | |
COR | 1.50 | 9.75 | 13.50 | 2.84 | 1.18 | 1.71 | 1.54 | |
CICOR | 0.86–2.61 | 4.55–20.89 | 2.92–62.48 | 1.28–6.32 | 0.53–2.63 | 0.74–3.99 | 0.86–2.74 | |
p | 0.567 NS | 0.000 S*** | 0.167 NS | 0.022 S* | 1.000 NS | 0.167 NS | 0.467 NS | |
B4 | DA | 0.87 | 0.84 | 0.87 | 0.87 | 0.62 | 0.68 | 0.52 |
CO | 0.85 | 0.58 | 0.32 | 0.85 | 0.48 | 0.62 | 0.50 | |
COR | 1.18 | 3.80 | 14.22 | 1.18 | 1.77 | 1.30 | 1.08 | |
CICOR | 0.53–2.63 | 1.95–7.40 | 3.38–59.84 | 0.53–2.63 | 1.01–3.10 | 0.73–2.33 | 0.62–1.89 | |
p | 1.000 NS | 0.006 S** | 0.206 NS | 1.000 NS | 0.383 NS | 0.824 NS | 1.000 NS | |
B5 | DA | 0.62 | 0.90 | 0.94 | 0.55 | 0.71 | 0.65 | 0.58 |
CO | 0.55 | 0.76 | 0.20 | 0.50 | 0.57 | 0.49 | 0.56 | |
COR | 1.33 | 2.84 | 62.67 | 1.22 | 1.85 | 1.93 | 1.09 | |
CICOR | 0.76–2.35 | 1.28–6.32 | 9.19–427.28 | 0.70–2.13 | 1.03–3.32 | 1.10–3.41 | 0.62–1.90 | |
p | 0.769 NS | 0.022 S* | 0.048 S* | 0.888 NS | 0.155 NS | 0.189 NS | 1.000 NS | |
C1 | DA | 0.90 | 0.84 | 0.90 | 0.90 | 1.00 | 1.00 | 1.00 |
CO | 0.84 | 0.50 | 0.60 | 0.40 | 0.60 | 1.00 | 1.00 | |
COR | 1.71 | 5.25 | 6.00 | 13.50 | inf | 1.00 | 1.00 | |
CICOR | 0.74–3.99 | 2.71–10.19 | 1.30–27.77 | 6.28–29.04 | - | - | - | |
p | 0.167 NS | 0.003 S** | 0.444 NS | 0.000 S*** | 0.000 S*** | 1.000 NS | 1.000 NS | |
C2 | DA | 0.81 | 1.00 | 0.94 | 0.94 | 1.00 | 1.00 | 0.94 |
CO | 0.71 | 0.40 | 0.80 | 0.68 | 1.00 | 1.00 | 0.92 | |
COR | 1.74 | inf | 3.92 | 7.37 | 1.00 | 1.00 | 1.36 | |
CICOR | 0.90–3.37 | - | 0.57–26.71 | 2.92–18.61 | - | - | 0.45–4.08 | |
p | 0.160 NS | 0.000 S*** | 1.000 NS | 0.002 S** | 1.000 NS | 1.000 NS | 1.000 NS | |
C3 | DA | 0.81 | 1.00 | 0.90 | 0.94 | 0.94 | 1.00 | 1.00 |
CO | 0.65 | 0.40 | 0.60 | 0.92 | 0.92 | 1.00 | 1.00 | |
COR | 2.30 | inf | 6.00 | 1.36 | 1.36 | 1.00 | 1.00 | |
CICOR | 1.20–4.38 | - | 1.30–27.77 | 0.45–4.08 | 0.45–4.08 | - | - | |
p | 0.047 S* | 0.000 S*** | 0.444 NS | 1.000 NS | 1.000 NS | 1.000 NS | 1.000 NS | |
C4 | DA | 0.81 | 1.00 | 0.90 | 0.81 | 1.00 | 1.00 | 1.00 |
CO | 0.65 | 0.40 | 0.60 | 0.71 | 1.00 | 1.00 | 1.00 | |
COR | 2.30 | inf | 6.00 | 1.74 | 1.00 | 1.00 | 1.00 | |
CICOR | 1.20–4.38 | - | 1.30–27.77 | 0.90–3.37 | - | - | - | |
p | 0.047 S* | 0.000 S*** | 0.444 NS | 0.160 NS | 1.000 NS | 1.000 NS | 1.000 NS | |
C5 | DA | 0.90 | 0.78 | 0.90 | 0.90 | 0.90 | 1.00 | 0.94 |
CO | 0.76 | 0.43 | 0.60 | 0.48 | 0.84 | 1.00 | 0.92 | |
COR | 0.76 | 0.43 | 0.60 | 0.48 | 0.84 | 1.00 | 0.92 | |
CICOR | 1.28–6.32 | 2.54–8.71 | 1.30–27.77 | 4.55–20.89 | 0.74–3.99 | - | 0.45–4.08 | |
p | 0.022 S* | 0.007 S** | 0.444 S* | 0.000 S*** | 0.167 NS | 1.000 NS | 1.000 NS |
aValues for method Ma were calculated from the results of 2 laboratories (vs 5 for other methods).
bRepeatability: is the probability of finding the same result from two identical test portions analyzed in the same laboratory, under repeatability conditions
cReproducibility: is the percentage chance of finding the same result for two identical samples analyzed in two different laboratories
dThe concordance odds ratio was calculated as the ratio DA x (1—CO)/CO x (1- DA). The larger the odds ratio (above 1), the more predominant the interlaboratory variation
eConfidence interval (95%) of the concordance odds ratio calculated with Woolf’s logit method
fThe shaded cells indicate statistical significance of variation between laboratories.
gp-value of Fisher’s exact test used to evaluate the statistical significance of the variation between laboratories: NS: not significant (p ≥ 0.05); S*: 0.01≤ p < 0.05; S**: 0.001 ≤ p < 0.01; S***: p < 0.001