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. 2017 Apr 6;8:14875. doi: 10.1038/ncomms14875

Table 2. Catalytic activities of I and II.

Inline graphic
Entry Ni–diamine–acetates Additive (x mol%) Yield (%)* d.r. e.e.
1 Mononuclear I 62 >50/1 90
2 Trinuclear II 52 >50/1 60
3 Trinuclear II§ 78 >50/1 60
4 Trinuclear II iPr2NH (10) 83 >50/1 90

*Yields are for isolated materials.

Determined by 1H NMR.

5 mol% of II (Ni-based) was used.

§5 mol% of II (MW-based) was used.