Table 5. Raman shifts and associated band assignments of cell line specific metabolites.
| Tissue | Metabolite | Raman Shift (cm−1) | Band Assignment |
|---|---|---|---|
| Spine | Dityrosine | 818 | Tyrosine, Proline, & Hydroxyproline, ν2PO2− stretch of nucleic acids |
| 1168 | Tyrosine: C-H in-plane bending | ||
| 1207 | Tyrosine & Phenylalanine: C-C6H5 stretching, Hydroxyproline | ||
| 1605 | Tyrosine & Phenylalanine: C=C in-plane bending | ||
| 1616 | Tyrosine & Tryptophan: C=C stretching mode | ||
| Gentisate Aldehyde | 804 | νC-C, νC-O | |
| 1133 | βC-H, νC-C | ||
| 1612 | νC-C, βC-H | ||
| 1o Tumor1 | L-Dihydroorotic Acid | 607 | βC=O, βC-Oca, βCrg-Cca |
| 652 | γNH, γOH | ||
| 734 | βC=Oca, νC-Oca, νrg, βC-Oca | ||
| 1131 | νNC, βCH1, νNC, | ||
| 1414 | νNC, βNH, νrg, βrg | ||
| L-Thyroxine | 1177 | Out-of-phase νCβ-O | |
| 1239 | In-phase νC-O, C-OHo.o.ph | ||
| 1381 | Stretching aromatic ring | ||
| 1537 | In-phase aromatic ring | ||
| 1579 | Stretching aromatic ring | ||
| Liver | 1-Phenylethylamine | 1031 | C-H in-plane bending mode, C-N stretching |
| 1327 | CH3 wagging mode | ||
| 1440 | CH3, CH deformation vibrations |
11o Tumor denotes Primary Tumor.