Table 2. Scope of the Sulfenoamination of Substrates with One-Methylene Tether.

^aIsolated yields of analytically pure material.

^bConstitutional selectivity determined by ¹H NMR spectroscopy of the crude mixture.

^cThe enantiomeric ratio of the major constitutional isomer was determined by CSP–HPLC analysis, and the absolute configurations of the products were assigned by comparison of their CD spectra with 3i.

^dReaction time of 6 d.