Table 2.
EPR data of solutions of thiazoles 1–4 with MB.[a]
| Thiazole | MB [equiv] | g value | A N [mT] | τ 1/2 [h][b] |
|---|---|---|---|---|
| 1 | 1 | 2.0030 | 0.72 | 91 |
| 2 | 1 | 2.0031 | 0.63 | 74 |
| 3 | 1 | 2.0034 | 0.78 | 385 |
| 4 | 1 | 2.0033 | 0.64 (one N atom) 0.34 (two N atom) 0.29 (eight H atom) | 3 |
| 3 | 2.0044 | 0.43 |
[a] In CH2Cl2 (distilled from P2O5), [solute]=1×10−4 m. The g and A N values were determined from spectral simulations. [b] Calculated by integrating the area of the EPR signals, normalized to the peak height of the signals from the Mn2+ marker as g standard.