Scheme 4.
Synthesis of 12‐hydroxyfarnesyl diphosphate (7) from commercially available farnesyl chloride 10. a) SeO2 (0.3 equiv), salicylic acid (0.3 equiv), tBuOOH (5 equiv), CH2Cl2, 0 °C. b) (Bu4N)3HP2O7 (2 equiv), CH3CN, room temperature.
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