Table 1. Summary of star polymers synthesized by the carbodiimide coupling of PHPMA block copolymers with compound 2 .
Entry | Linear polymer a | N arm b | M w,GPC c (g mol–1) | Đ c | Size d (nm) |
1 | PEG113-b-PHPMA10 | 6 | 4.11 × 104 | 1.23 | 27 |
2 | PEG113-b-PHPMA24 | 11 | 9.64 × 104 | 1.45 | 50 |
3 | PEG113-b-PHPMA70 | 47 | 7.88 × 105 | 1.36 | 60 |
4 | PEG113-b-PHPMA213 | Gelled | n/a | n/a | n/a |
a From Table S1, entries 1–4.
b Number of arms (N arm) per star polymer was calculated by the following equation: .
c Determined by GPC-MALLS, assuming dn/dc values identical to those of the linear polymer precursors (dn/dc values are listed in Table S1).
d Determined by DLS in aqueous solution.