Table 8. Spectrofluorimetric assessment of singlet oxygen generation by CURC and K2T23.
Solvent | [F(0)-F(10 min @ 280 nm)]/F(0) | [F(0)-F(10 min @ 420 nm)]/F(0) |
---|---|---|
Acetonitrile | 0.83 | 0.78 (0.04) |
Dimethylformamide | 0.55 | 0.59 (0.08) |
Methanol | 0.39 | 0.33 (0.03) |
Ethanol | 0.44 | 0.35 (0.02) |
Fractional fluorescence decrease of 9,10-dimethylanthracene in 10:1 dimethylanthracene:CURC mixtures in the solvents indicated in column 1 upon illumination of the sample with light at 280 nm (column 2) and 420 nm (column 3) for 10 minutes (see text for details). The results in parenthesis in column 3 were obtained with K2T23 as the photosensitizer.