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. 2017 Mar 21;3(4):322–328. doi: 10.1021/acscentsci.7b00085

Figure 3.

Figure 3

Pseudoenantiomeric character of the lowest energy transition states for cyclization from the corresponding anionic hemiaminals of Phe-I for (R,S) d-ribose and (S,R) d-lyxose. Light blue arrow shows O–C distance for attack of carbonyl oxygen on nitrile carbon.