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. 2017 Mar 21;3(4):322–328. doi: 10.1021/acscentsci.7b00085

Table 1. Enantioenrichment of Amino Acid Precursors Driven by d-Sugars (Scheme 3)a.

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a

Reaction conditions: 0.25 M AM-I with 0.50 M sugar in H2O with 0.25 M NaOH at 22–24 °C; Ala-I (7 d), Phe-I (7 d), Trp-I (5 d). For reactions employing mixtures of sugars: 0.25 M in each sugar; Ala-I (8 d), Phe-I (7 d), Trp (7 d). Enantiomeric excess measured using chiral HPLC after derivatization of AM-II.