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. Author manuscript; available in PMC: 2018 Jan 1.
Published in final edited form as: Drug Test Anal. 2016 Apr 21;9(1):115–126. doi: 10.1002/dta.1974

Table 2.

Electron ionization mass spectral data

No. R′ R″ M.+ [M-41]+ [C9H6NR′R″]+ [C10H8NR′R″]+, [C10H7NR′R″].+ [C8H4NR′R″]+, [C8H3NR′R″].+ Other fragments
1 H H 240 199 130 144, 143 116, 115 --
2 H Ph 316 275 206 220, 219 192, 191 --
3 4-AcO H 298 257 188 202, 201 174, 173 256 (M - C2H2O), 239 (M - .OAc), 160 (188 - CO), 146 (188 - C2H2O)
4 4-OH H 256 215 146 160, 159 132, 131 --
5 4,5-ED a H 298 257 188 202, 201 176, 175 160 (188 - C2H4), 132 (160 - CO)
6 5-CH3 H 254 213 144 158, 157 130, 129 --
7 5-OCH3 H 270 239 160 174, 173 146, 145 239 (M - .OCH3), 145 (160 - .CH3), 240 (M - CH2O), 130 (160 - CH2O), 117 (145 - CO)
8 5-OCH3 CH3 284 243 174 188, 187 160, 159 253 (M - .OCH3), 159 (174 - .CH3), 144 (174 - CH2O), 131 (159 - CO)
9 5-OC2H5 H 284 241 174 188, 187 160, 159 269 (M - .CH3), 239 (M - C2H5O.), 146 (174 - C2H4)
10 5-F H 258 217 148 162, 161 134, 133 --
11 5-F CH3 272 231 162 176, 175 148, 147 --
12 5-Cl H 274/276 233/235 164/166 178/180, 177/179 150/152, 149/147 239 (M - Cl.)
13 5-Br H 318/320 277/279 208/210 222/220, 221/223 194/192, 193/191 239 (M - Br.)
14 5,6-MD b H 284 243 174 188, 187 160, 159 228, 144 (174 - CH2O)
15 6-F H 258 217 148 162, 161 134, 133 --
16 7-CH3 H 254 213 144 158, 157 130, 129 --
17 7-C2H5 H 268 227 158 172, 171 144, 143 239 (M - C2H5.)
a

4,5-(OCH2CH2O): 4,5-ethylenedioxy

b

5,6-(OCH2O): 5,6-methylenedioxy.