Table 2.
No. | R′ | R″ | M.+ | [M-41]+ | [C9H6NR′R″]+ | [C10H8NR′R″]+, [C10H7NR′R″].+ | [C8H4NR′R″]+, [C8H3NR′R″].+ | Other fragments |
---|---|---|---|---|---|---|---|---|
1 | H | H | 240 | 199 | 130 | 144, 143 | 116, 115 | -- |
2 | H | Ph | 316 | 275 | 206 | 220, 219 | 192, 191 | -- |
3 | 4-AcO | H | 298 | 257 | 188 | 202, 201 | 174, 173 | 256 (M - C2H2O), 239 (M - .OAc), 160 (188 - CO), 146 (188 - C2H2O) |
4 | 4-OH | H | 256 | 215 | 146 | 160, 159 | 132, 131 | -- |
5 | 4,5-ED a | H | 298 | 257 | 188 | 202, 201 | 176, 175 | 160 (188 - C2H4), 132 (160 - CO) |
6 | 5-CH3 | H | 254 | 213 | 144 | 158, 157 | 130, 129 | -- |
7 | 5-OCH3 | H | 270 | 239 | 160 | 174, 173 | 146, 145 | 239 (M - .OCH3), 145 (160 - .CH3), 240 (M - CH2O), 130 (160 - CH2O), 117 (145 - CO) |
8 | 5-OCH3 | CH3 | 284 | 243 | 174 | 188, 187 | 160, 159 | 253 (M - .OCH3), 159 (174 - .CH3), 144 (174 - CH2O), 131 (159 - CO) |
9 | 5-OC2H5 | H | 284 | 241 | 174 | 188, 187 | 160, 159 | 269 (M - .CH3), 239 (M - C2H5O.), 146 (174 - C2H4) |
10 | 5-F | H | 258 | 217 | 148 | 162, 161 | 134, 133 | -- |
11 | 5-F | CH3 | 272 | 231 | 162 | 176, 175 | 148, 147 | -- |
12 | 5-Cl | H | 274/276 | 233/235 | 164/166 | 178/180, 177/179 | 150/152, 149/147 | 239 (M - Cl.) |
13 | 5-Br | H | 318/320 | 277/279 | 208/210 | 222/220, 221/223 | 194/192, 193/191 | 239 (M - Br.) |
14 | 5,6-MD b | H | 284 | 243 | 174 | 188, 187 | 160, 159 | 228, 144 (174 - CH2O) |
15 | 6-F | H | 258 | 217 | 148 | 162, 161 | 134, 133 | -- |
16 | 7-CH3 | H | 254 | 213 | 144 | 158, 157 | 130, 129 | -- |
17 | 7-C2H5 | H | 268 | 227 | 158 | 172, 171 | 144, 143 | 239 (M - C2H5.) |
4,5-(OCH2CH2O): 4,5-ethylenedioxy
5,6-(OCH2O): 5,6-methylenedioxy.