Skip to main content
. 2017 Apr 24;9(8):1413–1421. doi: 10.1002/cctc.201601568

Table 6.

Substrate scope with the variation of both the tosylhydrazone salt and the alkene.[a] Inline graphic

Entry R1 Alkene Product Yield [%] trans/cis
1 Ph graphic file with name CCTC-9-1413-g007.jpg graphic file with name CCTC-9-1413-g048.jpg 94 78:22
2 CN graphic file with name CCTC-9-1413-g007.jpg graphic file with name CCTC-9-1413-g049.jpg 68 70:30
3 NO2 graphic file with name CCTC-9-1413-g007.jpg graphic file with name CCTC-9-1413-g050.jpg 63 72:28
4 OMe graphic file with name CCTC-9-1413-g007.jpg graphic file with name CCTC-9-1413-g051.jpg 94 74:26
5 iPr graphic file with name CCTC-9-1413-g007.jpg graphic file with name CCTC-9-1413-g052.jpg 97 75:25
6 iPr graphic file with name CCTC-9-1413-g008.jpg graphic file with name CCTC-9-1413-g055.jpg 93 73:26
7 iPr graphic file with name CCTC-9-1413-g026.jpg graphic file with name CCTC-9-1413-g056.jpg 96 75:25
8 iPr graphic file with name CCTC-9-1413-g053.jpg graphic file with name CCTC-9-1413-g057.jpg 77 62:38
9 iPr graphic file with name CCTC-9-1413-g030.jpg graphic file with name CCTC-9-1413-g058.jpg 89 89:11
10 iPr graphic file with name CCTC-9-1413-g034.jpg graphic file with name CCTC-9-1413-g059.jpg 90 86:14
11 iPr graphic file with name CCTC-9-1413-g054.jpg graphic file with name CCTC-9-1413-g060.jpg 85 90:10

[a] Reactions were performed under N2 with 1.0 equiv. of sodium tosylhydrazone, 3.0 equiv. alkene, 0.15 equiv. Aliquat®336 and 3 mol % [Co(MeTAA)]. Concentration: 0.675 mmol sodium tosylhydrazone/5 mL THF solvent.