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. 2017 Apr 11;121(16):8760–8769. doi: 10.1021/acs.jpcc.7b01577

Table 2. Parameters Used to Construct the VRBE Diagram for RE2O2S with U = 6.37 eVa.

sample Eex ECT(Eu3+) ECT(Ti4+) EV EC ETb3+ EPr3+
La2O2S 4.57 3.61 3.79 –7.38 –2.44 –6.57 –6.75
Gd2O2S 4.66 3.72 3.65 –7.49 –2.46 –6.57 –6.75
Y2O2S 4.67 3.75 3.53 –7.52 –2.48 –6.57 –6.75
Lu2O2S 4.66 3.77 3.44 –7.54 –2.51 –6.57 –6.75
a

All numbers are in eV.