Fig. 2. ORTEPs of (PNP)Rh CF₂ (left) and (PNP)Rh(C₂F₄) (right). The ellipsoids are set at the 50% probability level, and hydrogen atoms are omitted for clarity. Selected bond distances (Å) and angles (°) for (PNP)Rh CF₂: Rh1–C1, 1.821(4); Rh1–N1, 2.043(3); C1–F1, 1.335(4); C1–F2, 1.348(5); N1–Rh–C1, 171.39(15); F2–C1–F1, 100.8(3); Rh1–C1–F2, 130.1(3); Rh1–C1–F1, 128.6. (PNP)Rh(C₂F₄): Rh1–C14, 2.006(3); Rh1–N1, 2.054(3); C14–F1, 1.378(3); C14–F2, 1.361(3); C14–C14′, 1.354(7); C14–Rh–C14′, 39.4(2); C14–Rh–N1, 160.28(10).