Fig. 2. Molecular view of (dadi)TiPMe2Ph (1-PMe2Ph). Interatomic distances (Å) and angles (°): Ti–P, 2.6049(7); Ti–N1, 2.0029(18); Ti–N2, 2.0194(18); Ti–N3, 2.0332(18); Ti–N4, 2.0088(18); N1–C13, 1.411(3); C13–C18, 1.413(3); N2–C18, 1.396(3); N2–C19, 1.379(3); C19–C20, 1.338(3); N3–C20, 1.381(3); N3–C21, 1.396(3); C21–C26, 1.408(3); N4–C26, 1.406(3); P–Ti–N1, 114.64(6); P–Ti–N2, 85.21(5); P–Ti–N3, 85.23(5); P–Ti–N4, 102.35(5); N1–Ti–N2, 78.10(7); N1–Ti–N3, 143.60(7); N1–Ti–N4, 123.37(7); N2–Ti–N3, 73.38(7); N2–Ti–N4, 148.83(7); N3–Ti–N4, 77.14(7).
