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DKP fungal natural product brevianamide F (cyan sticks) bound to prenyltransferase (gray sticks) (PDB ID 3O2K).2 Noteworthy is the fact that the DKP NH undergoes a hydrogen-bond-donor−π interaction (yellow dotted lines) to the Met backbone carbonyl. Hydrogen-bonding, van der Waals, dipolar, and π–π interactions are shown using red, yellow, cyan, and orange dotted lines, respectively. The stereopicture was rendered using PYMOL.3
