Table 2. Glycosylation of donors 1–3 with carbohydrate acceptors.
Acceptor | |||
Product, α : β (yield) c | Product, α : β (yield) c | Product, α : β (yield) c | |
20 | 25 | 30 | |
1 : 10 | 1 : 3 | <1 : 20 | |
(97%) | (81%) | (71%) | |
21 | 26 | 31 | |
1 : 9 | 1 : 1 | <1 : 20 | |
(75%) | (79%) | (61%) | |
22 | 27 | 32 | |
1 : 10 | 5 : 1 | 1 : 10 | |
(87%) | (90%) | (71%) | |
23 | 28 | 33 | |
<1 : 20 | >20 : 1 | <1 : 20 | |
(70%) | (83%) | (76%) | |
24 | 29 | 34 | |
<1 : 20 | >20 : 1 | 1 : 7 | |
(87%) | (80%) | (80%) |