Table 1. Statistically corrected stability constants K 1, K 2 and K 3, as defined in Fig. 3, measured in CH2Cl2 at 298 K for pyridine + CPDIPS-ZnP1 (K 1), NiP2 + CPDIPS-ZnP2 (K 2) and NiP4 + CPDIPS-ZnP4 (K 4). These values of K 1, K 2 and K 3 were used to calculate the values of EM1, (EM2EM3)0.5, β 1 : 1, β 1 : 2, β 2 : 2 and β 2 : 3 as explained in Fig. 3 and 5 .
K 1 | (1.4 ± 0.1) × 104 M–1 |
K 2 | (5.0 ± 0.7) × 108 M–1 |
K 4 | (1.8 ± 0.6) × 1018 M–1 |
EM1 | 0.3 ± 0.1 M |
(EM2EM3)0.5 | 2.1 ± 0.4 M |
β 1 : 1 | (5.4 ± 1.6) × 1018 M–1 |
β 1 : 2 | (1.8 ± 0.8) × 1027 M–2 |
β 2 : 2 | (8.9 ± 5.2) × 1035 M–3 |
β 2 : 3 | (8.1 ± 7.1) × 1053 M–4 |