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. 2017 Apr 4;7:612. doi: 10.1038/s41598-017-00574-1

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© The Author(s) 2017

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Characterization of the photocatalytic conversion mechanism in Re-MOF-NH₂ (33%). (a) EXAFS spectra for Re-MOF, Re-MOF-NH₂ (33%) and Re-MOF-NH₂ (80%). (b) Electrostatic potential diagram for Re-MOF-NH₂ (33%) where the ReTC inside is asymmetric. (c) IR spectra of Re-MOF-NH₂ (33%) under vacuum and CO₂ atmosphere. (d) Difference IR spectra of Re-MOF, Re-MOF-NH₂ (33%) and Re-MOF-NH₂ (80%) in the presence of CO₂. (e) Electrostatic potential diagram of the intermolecular stabilization of carbamate by the -NH₂ functional groups before making CO in Re-MOF-NH₂ (33%).