Table 1. 1H (600 MHz) and 13C (100 MHz) NMR Data for Compounds 1 and 2 in DMSO-d6.
1 |
2 |
|||
---|---|---|---|---|
no. | δC | δH, mult. (J in Hz) | δC | δH, mult. (J in Hz) |
1 | 159.8, C | 159.9, C | ||
2 | 89.0, CH | 6.73, s | 88.3, CH | 6.79, s |
3 | 155.3, C | 155.5, C | ||
4 | 57.7, CH | 4.55, qd (6.7, 6.6) | 54.3, CH | 4.65, qd (6.9, 6.6) |
5 | 64.1, CH | 4.43, ddd (8.8, 8.0, 6.7) | 24.7, CH2 | 2.21, m; 1.71, m |
6 | 39.3, CH2 | 2.67, dd (16.9, 8.0); | 31.4, CH2 | 2.84, m; 2.45, m |
2.63, dd (16.9, 8.8) | ||||
7 | 173.4, C | 176.0, C | ||
8 | 13.3, CH3 | 1.23, d (6.5) | 20.0, CH3 | 1.31, d (6.4) |
1′ | 163.7, C | 163.7, C | ||
2′ | 116.2, CH | 5.98, m | 116.2, CH | 5.98, m |
3′ | 158.7, C | 158.7, C | ||
4′ | 28.0, CH3 | 2.03, d (1.2) | 28.1, CH3 | 2.03, s |
5′ | 21.0, CH3 | 2.25, d (1.2) | 21.1, CH3 | 2.25, s |