Table 3. Copolymerisation of limonene oxide and carbon dioxide with catalyst 1 under different reaction conditions ^a .

Entry	[LO] : [1]	% trans LO	V (tol) [mL]	Pressure [bar]	Temperature [°C]	Time [h]	Yield [%]	Yield trans-LO [%]	trans/cis*/trans* b [%]	TOF c , d	M n (PDI) e [g mol–1]
1	250	84	2	30	25	16	68	81	100 : 0 : 0	60 c	62.000 (1.7)
2	250	84	2	30	40	16	73	88	99.6 : 0.3 : 0	180 c	32.500 (1.9)
3	250	84	2	30	60	16	17	20	94 : 5 : 1	40 c	4.300 (1.6)
4	250	54	2	30	40	16	51	94	96 : 2 : 2	110 c	10.000 (1.3)
5	250	54	2	30	60	16	11	21	95 : 3 : 2	30 c	7.200 (1.7)
6	250	>99	2	30	40	6.5	59	59	100 : 0 : 0	120 c	145.300 (1.3)
7	250	>99	2	30	60	16	26	26	97 : 3 : 0	110 c	56.100 (2.5)
8	500	84	2	30	40	16	46	55	97 : 3 : 0	110 c	19.000 (2.5)
9	500	84	0	30	40	3	35	42	99 : 1 : 0	60 d	24.000 (1.9)
10	500	84	0	30	60	0.66	20	24	95 : 5 : 0	130 d	4.900 (1.9)
11	500	84	0	30	80	3	0	0	—	—	—
12	500	84	0	10	60	3	0	0	—	—	—
13	500	84	0	50	60	0.5	30	36	98 : 2 : 0	310 d	12.800 (1.8)
14	500	84	0	50	60	16	40	50	96 : 4 : 0	15 d	9.500 (2.6)
15	1000	84	0	50	60	3.5	13	16	95 : 5 : 0	40 d	6.000 (2.1)

^a Volume (LO) = 5.0 mL (30.5 mmol).

^b Selectivity for trans/cis*/trans*-PLimC was determined by ¹³C NMR spectroscopy (ESI).

^c In situ TOF is determined by a calibration curve S5, intensity ν(C O) vs. n(PLimC).

^d TOF is defined as TON/time.

^e Determined by GPC, calibrated with polystyrene standards in chloroform.