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. 2010 Jun 30;3(7):3818–3844. doi: 10.3390/ma3073818

Table 5.

Separation of SWNTs by selective reaction.

Reference Separated object SWNTs Chemicals
[130,168] M/S HiPco H2O2/water at 90 °C
[169] diameter, (n, m) HiPco air at 450 °C, H2O2/water at 90 °C
[170] diameter HiPco H2O2, light irradiation
[171] (n, m) HiPco, CoMoCAT H2O2, SC or SC/SDS in D2O
[172] diameter HiPco H2O2 + light
[173] M/S HiPco OsO4, UV
[182] M/S AD NaClOx/1-methyl-2-pyrrolidone
[174] M/S, diameter HiPco acid mixture (H2SO4/HNO3) under microwave irradiation
[175] M/S HiPco acid mixture (H2SO4/HNO3)
[176,177] diameter HiPco acid mixture (H2SO4/HNO3) at 35–55 °C under sonication
[178] M/S HiPco HNO3 at 135 °C
[179,180] diameter HiPco ozone in methanol at −78 °C
[181] (6, 5) HiPco AuCl4, SC/water
[183] diameter LV air at 350–550 °C, HNO3 at 120 °C
[184] HiPco air at 460–620 °C
[185,186] M/S HiPco NO2SbF6 or NO2BF4 in tetramethylene sulfone/chloroform
[187] M/S, diameter SWNTs NO2
[188,189] M/S HiPco dichlorocarbene in dichlorobenzene
[190,194,197,198,199] M/S HiPco diazonium salt/water
[191] M/S AD diazonium salt of 4-heptadecafluorooctyl-aniline/perfluorohexane
[192,195] M/S HiPco, AD 4-nitrobenzenediazonium salt in DMF, 4-aminobenzylamine
[193,200] M/S CVD 4-bromobenzenediazonium tetrafluoroborate in water
[58,109,201] M/S HiPco 4-hydroxybenzenediazonium salt
[196] M/S HiPco SC, 4-dodecyloxybenzenediazonium tetrafluoroborate in water
[202] M/S, diameter HiPco SDS, 4-chloro- and 4-nitrophenyldiazonium salts in water
[203] M/S, diameter HiPco fluorine gas
[204] M/S HiPco triethylsilane at room temperature
[205] M/S HiPco perfluoro 2-(fluorosulfonylethoxy)propyl vinyl ether at 215 °C
[206] M/S HiPco SO3 at 400 °C
[130,208] M/S HiPco azomethine ylide/THF at 65 °C
[207] M/S, diameter HiPco RLi, RMgX in cyclohexane
[209,210,211] M/S MWNTs, SWNTs current-induced electrical breakdown
[212] M/S CVD methane plasma at 400 °C/annealing at 600 °C
[213] M/S AD hydrogen plasma
[214] (n, m) CVD laser irradiation
[215] M/S CoMoCAT, HiPco, LV laser irradiation
[218] M/S Fe-catalyzed CVD Xe lamp
[216] CoMoCAT microwave irradiation
[174,217] M/S, diameter HiPco microwave irradiation
[219] diameter HiPco Li at 473 °C
[220] (n, m) HiPco SDS in D2O/salt (NaCl, MgSO4, ErCl3)
[221] diameter HiPco LiClO4, (CH3)4NBF4, n-Bu4NClO4, n-Oct4NClO4, ionic liquid in CH3CN
[222] M/S AD aromatic or aliphatic solvent with electron-withdrawing or -donating groups
[223] (n, m) HiPco TCNQ, TFTCNQa, mordant yellow 10 and ABb
[224] M/S (10, 0), (6, 6) naphthalene, anthracene, TCNQ and DDQ

a 2, 3, 5, 6-tetrafluoro-7, 7, 8, 8-tetracyanoquinodimethane, b 4-amino-1, 1-azobenzene-3, 4-disulfonic acid.