Table 1.

Catalysis results by PdNP-1 for the biphasic reaction of 1-octen-3-ol.^a

Entry	Mole % PdNP-1	Time (h)	Conversionc (%)	Catalysis yield (%)c
				Isomerization	Hydrogenation	Hydrogenolysis
1	5	24	25	5	20	0
2	10	24	45	10	35	0
3b	10	24	100d	27	73	0

^aThe reactions were performed under atmospheric pressure and at room temperature.

^bExcess H₂ gas was provided using a balloon attachment.

^cThe product ratios and conversion yield were determined by analysing the ¹H NMR integration results.

^dTurn-over-frequency (TOF) based on the active sites on PdNP surface was estimated to be 1.43 site⁻¹hr⁻¹.