Table 3.
Entry | Allylic alcohols | Catalysis yields (%)a
|
|
---|---|---|---|
Isomerization | Hydrogenation | ||
i | 1-octen-3-ol | 27(36)b | 73(64)b |
ii | 1-nonen-3-ol | 42(33)b | 58(67)b |
iii | 1-decen-3-ol | 57(52)b | 43(48)b |
The product ratios were determined by analysing the 1H NMR integration results.
The yields in parentheses are obtained from the catalytic reactions of PdNP-2.