Table 3.

¹H (900 MHz) and ¹³C (225 MHz) NMR Spectroscopic Data of Compounds 5 and 6^a,^b

unit/ring	no.	5		6		unit/ring	no.	5		6
		δC, mult	δH (J, Hz)	δC, mult	δH (J, Hz)			δC, mult	δH (J, Hz)	δC, mult	δH (J, Hz)
unit I						unit III
C	2	99.98, C		100.00, C		I	2	84.53, CH	4.6620, ddd (8.2, 0.1,–0.5)	100.38, C
	3	68.59, CH	4.0246, d (3.1)	68.48, CH	3.9870, d (3.0)		3	68.46, CH	4.0860, ddd (8.7, 8.2, 5.7)	67.73, CH	4.0867, d (3.4)
	4	29.82, CH	4.6816, d (3.1)	29.78, CH	4.6718, d (3.0)		4	29.58, CH2	3.0091, dd (−16.5, 5.7) 2.5730, ddd (−16.5, 8.7,0.5)	29.63, CH	4.3001, d (3.4)
A	5	157.84, C		157.90, C		G	5	156.13, C		150.70, C
	6	97.74, CH	6.0059, d (2.4)	97.74, CH	6.0327, d (2.3)		6	96.28, CH	6.0862, s	110.18, C
	7	158.11, C		158.15, C			7	152.70, C		152.96, C
	8	96.33, CH	6.0483, d (2.4)	96.34, CH	6.0610, d (2.3)		8	107.33, C		97.27, CH	6.2523, s
	9	154.33, C		154.35, C			9	151.12, C		152.73, C
	10	103.67, C		103.55, C			10	103.28, C		106.36, C
B	1′	132.67, C		132.62, C		H	1′	130.79, C		132.09, C
	2′	115.42, CH	7.0972, dd (2.2, 0.2)	115.21, CH	7.0325, dd (2.2, 0.2)		2′	116.03, CH	6.9638, ddd (2.1, −0.5, <0.1c)	*115.59, CH	7.1191, dd (2.2, < 0.1c)
	3′	145.61, C		145.56, C			3′	146.76, C		145.72, C
	4′	146.27, C		146.65, C			4′	146.70, C		146.92, C
	5′	115.64, CH	6.7815, dd (8.3, 0.2)	*115.61, CH	6.7469, dd (8.4, 0.2)		5′	116.26, CH	6.8303, dd (8.2, < 0.1c)	*115.60, CH	6.8077, dd (8.3, <0.1c)
	6′	119.65, CH	6.9929, dd (8.3, 2.2)	119.76, CH	6.9858, dd (8.4, 2.2)		6′	120.73, CH	6.8829, dd (8.2, 2.1)	119.83, CH	7.0109, dd (8.3, 2.2)
unit II						unit IV
F	2	100.76, C		100.95, C		L	2			85.00, CH	4.6119, ddd (9.1, −0.2, 0.1)
	3	67.82, CH	4.0997, d (3.2)	67.57, CH	4.1187, d (3.1)		3			68.01, CH	4.2543, ddd (9.1,9.1,6.1)
	4	29.65, CH	4.3194, d (3.2)	30.15, CH	4.3878, d (3.1)		4			30.61, CH2	3.1288 dd (−16.4, 6.1) 2.5768, ddd (−16.4, 9.1,0.1)
D	5	155.85, C		155.51, C		J	5			156.31, C
	6	98.12, CH	6.1168, s	98.11, CH	6.1955, s		6			96.61, CH	6.0824, s
	7	153.45, C		153.56, C			7			152.26, C
	8	108.80, C		109.12, C			8			106.38, C
	9	148.97, C		148.89, C			9			151.69, C
	10	105.42, C		105.19, C			10			103.71, C
E	1′	132.41, C		132.31, C		K	1′			130.22, C
	2′	115.50, CH	7.4033, dd (2.2, 0.2)	115.53, CH	7.4221, dd (2.2, < 0.1c)		2′			117.27, CH	7.0656, ddd (2.0, −0.2, 0.2)
	3′	145.61, C		145.62, C			3′			146.23, C
	4′	146.89, C		146.86, C			4′			147.06, C
	5′	115.68, CH	6.8809, dd (8.3, 0.2)	115.70, CH	6.8914, dd (8.3, < 0.1c)		5′			116.69, CH	6.9201, dd (8.2, 0.2)
	6′	120.30, CH	7.4232, dd (8.3, 2.2)	120.34, CH	7.4374, dd (8.3, 2.2)		6′			121.04, CH	7.0707, dd (8.2, 2.0)

^a1H and ¹³C NMR data were acquired in methanol-d₆ at 298 K at 900 and 225 MHz, respectively.

^bThe δ_H and J values including their signs were generated via ¹H iterative full spin analysis (HiFSA).¹¹

^cVery small couplings were detected by HiFSA (for pms profiles, see the Supporting Information) and are essential for the line overall fit. Asterisks indicate that the signals are interchangeable.