Table 1.
Relevant parameters obtained from the X-ray photoelectron spectroscopy (XPS) data analysis represented in Figure 5: energies and integral amplitudes for each separate component used in the fit. The corrected amplitudes (Acorr) are obtained by dividing the integral amplitudes (A) by the Wagner atomic sensitivity factors [60]. The binding energies (BE) represented are that of the maximum angular moment line from each doublet: jmax = 3/2 for 2p states and 5/2 for 3d states. Experimental errors are of the order of ± the least significant digit of each binding energy or integral amplitude.
Sample | Level | Ge 3d | Ge 2p | Mn 2p | ||||||
---|---|---|---|---|---|---|---|---|---|---|
| ||||||||||
Component | (1) | (2) | (3) | (1) | (2) | (3) | (1) | (2) | (3) | |
Clean | BE jmax(eV) | 29.413 | 29.829 | 28.820 | 1217.62 | 1218.64 | 1216.37 | – | – | – |
A(eV·kcps) | 8.70 | 0.94 | 0.33 | 175.42 | 12.36 | 9.43 | – | – | – | |
| ||||||||||
Ge(001) (2 × 1) | Acorr(eV·kcps) | 22.89 | 2.47 | 0.87 | 19.17 | 1.35 | 1.03 | – | – | – |
Acorr, total | 26.23 | 21.55 | – | |||||||
| ||||||||||
MnGe (001) | BE jmax (eV) | 29.243 | 29.886 | – | 1217.40 | 1218.55 | – | 638.50 | 639.24 | 640.61 |
A(eV·kcps) | 4.33 | 0.49 | – | 110.66 | 7.52 | – | 4.29 | 7.64 | 5.87 | |
Acorr(eV·kcps) | 11.39 | 1.29 | – | 12.09 | 0.82 | – | 1.65 | 2.94 | 2.26 | |
Acorr, total | 12.68 | 12.91 | 6.85 |