Table 1.
MOFs Synthesized from Hydrothermal Conditions.
| MOF Class | Metal Center | Organic Linker | Mineralizing Agent | Temperature (°C) | Time (h) | Pore Diameter (Å) | Space Group | Bravis Lattice | Reference |
|---|---|---|---|---|---|---|---|---|---|
| MIL-47 | VCl3 | BDC | – | 200 | 96 |
as: 7.9 × 12.0 ht: 10.5 × 11.0 |
as: Pnma ht: Pnma |
as: orthorhombic ht: orthorhombic |
[47] |
| MIL-53 | Al(NO3)3·9H2O | BDC | – | 220 | 72 |
as: 7.3 × 7.7 ht: 8.5 × 8.5 lt: 2.6 × 13.6 |
as: Pnma ht: Imma lt: Cc |
as: orthorhombic ht: orthorhombic lt: monoclinic |
[26] |
| MIL-69 | NDC | KOH | 210 | 16 | H: 2.7 × 19.4 DeH: 8.5 × 8.5 |
C2/c | Monoclinic | [48] | |
| MIL-96 | BTC | – | 210 | 24 | Cavity free: 8.8 Pore opening: 2.5–3.5 |
P63/mmc | Hexagonal | [49] | |
| MIL-100 | Fe metal | HF | 160 | 8 | Cage: 25. 29 Window: 5, 9 |
Fdm | Cubic | [50,51] | |
| HNO3 | 12 | – | – | – | [45] | ||||
| FeCl3 6H2O | – | ||||||||
| Fe(NO3)3 9H2O | |||||||||
| Al(NO3)3·9H2O | HNO3 | 210 | 3.5 | 5.2 × 8.8 | Fd3m | Cubic | [52] | ||
| Cr metal | HF | 220 | 96 | Internal: 6.6; External: 25 | [50] | ||||
| MIL-110 | Al(NO3)3·9H2O | HNO3 | 210 | 72 | 16 | P6322 | Hexagonal | [53] | |
| MIL-118 | Al(NO3)3·9H2O | H4BTEC | – | 210 | 24 |
as: 7.3 × 7.7 ht: 8.5 × 8.5 lt: 2.6 × 13.6 |
as: C2/c ht: Pbam lt: Pnam |
as: monoclinic ht: orthorhombic lt: rthorhombic |
[54] |
| MIL-120 | Al(NO3)3·9H2O | H4BTEC | NaOH | 210 | 24 | 5.4 × 4.7 | C2/c | monoclinic | [55] |
| MIL-121 | Al(NO3)3·9H2O | H4BTEC | – | 210 | 24 | 8.7 × 5.7 | C2/c | monoclinic | [40] |
| MIL-122 | Al(NO3)3·9H2O | H4NTC | – | 210 | 24 | – | P21/c | monoclinic | [56] |
| Ga(NO3)3·xH2O | |||||||||
| * | In(NO3)3·5H2O | ||||||||
| CuSO4·5H2O | L | KBr | 85 | 1.5 | Hydrated: 18.99 × 15.14 Dehydrated: 18.56 × 12.81 |
P | triclinic | [11] | |
| Cu-MOF-SiF6 | CuSiF6 | BPED | – | rt | 72 | 13.5 × 13.5 | P4/ncc | Tetragonal | [57] |
| ELM-12 | Cu(OTf)2 | 4,4′-bpy | MeOH | rt | >168 | 11 × 11.5 | Pbna | Orthorhombic | [58] |
| EtOH | Pn21a | ||||||||
| 1-PrOH | Pnna | ||||||||
| 1-BuOH | |||||||||
| * | Cu(NO3)3·3H2O | HDHBC 4,4′-bpy | Diethyl ether | rt | a few days | 3.6 × 4.2 | P2/c | Monoclinic | [59] |
4,4′-bpy = 4,4′-bipyridine; BDC = 1,4-benzene-dicarboxylic acid; BTC = 1,3,5-benzene-tricarboxylic acid; BPED = meso-1,2-bis(4-pyridyl)-1,2-ethanediol; H4BTEC = 1,2,4,5-benzene-tetracarboxylic acid; H4NTC = 1,4,5,8,-naphthalene-tetracarboxylic acid; HDHBC = 2,5-dihydroxybenzoic acid; L = 4,4′-(1,4-(trans-2-butene)diyl)bis(1,2,4-triazole); NDC = 2,6-naphthalene-dicarboxylic acid; OTf = trifluoromethanesulfonate; rt: room temperature
*
haven’t been named.