Table 2.

MOFs Synthesized from Solvothermal Conditions.

MOF Class	Metal Center	Organic Linker	Solvent	Mineralizing Agent	Temprature (°C)	Time (h)	Pore Diameter (Å)	Space Group	Bravis Lattice	Reference
MOF-5	Zn(NO3)2·6H2O	BDC	DMF	C6H15N; C6H5Cl; H2O2	rt	0.5–4	8	Fm3m	Cubic	[60,61]
	Zn(OAc)2·2H2O	BDC	DMF	C6H15N	rt	2.5	7.56	Fm3m	Cubic	[62]
MOF-74	Zn(OAc)2·2H2O	H4DHTP	DMF	–	rt	18	–	–	–	[62]
	Zn(NO3)2·4H2O			2-Propanol H2O	105	20	10.3 × 5.5	$R\overline{3}$	Trigonal	[63]
MOF-177	Zn(NO3)2·6H2O	H3BTB	DEF	–	100	23	10.8	$P\overline{3}1c$	Trigonal	[62,64]
MOF-199 (HKUST-1)	Cu(NO3)2·2.5H2O	BTC	DMF	C6H15N; EtOH; H2O	85	24	Cage: 13.2 × 11.1; Aperture: 6.9	Fm3m	Cubic	[64–66]
IR-MOF-0	Zn(OAC)2·2H2O	ADC	DMF	C6H15N	rt	over-night	–	Fm3m	Cubic	[62]
MIL-88	FeCl3·6H2O	BDC	DMF	–	150	0.2	3 × 14	$P\overline{6}2c$	Hexagonal	[67,68]
*	Co(CF3SO3)2	H2BDP	DEF	–	150	144	–	C2/c	Monoclinic	[69]
CFA2	Cu(OAc)2·H2O	H2PHBPZ	DEF; MeOH	–	110	72	12–14.5	I41/a	Tetragonal	[70]
CFA3	Ag2O	H2PHBPZ	EtOH	NH4OH	rt	120	–	P21/c	Monoclinic	[70]
*	Zn(NO3)2·6H2O	TCPOM 4,4′-bpy	DMF	–	100	24	–	C2/c	Monoclinic	[71]
*	Zn(NO3)2·6H2O	BDC DABCO	DMF	–	120	48	7.5 × 7.5	I4/mcm	Tetragonal	[72,73]
*	Cd(NO3)2·4H2O	BPNDC 4,4′-bpy	DMF	–	120	24	Cavity: 12 × 7 × 4; Aperture: 2 × 6	C2/c	Monoclinic	[74]
*	La(NO3)2·6H2O	H3BTB	DMF	–	95	48	–	P6522	Hexagonal	[75]
*	Zn(NO3)2·6H2O	2,5-BME-BDC; DABCO	DMF	–	120	48	–	C2/m	Monoclinic	[76]
*	Zn(NO3)2·6H2O	2,3-BME-BDC; DABCO	DMF	–	120	48	–	C2/m	Monoclinic	[76]
*	Zn(NO3)2·6H2O	DE-BDC; DABCO	DMF	–	120	48	–	C2/m	Monoclinic	[76]
*	Zn(NO3)2·6H2O	DP-BDC; DABCO	DMF	–	120	48	–	C2/m	Monoclinic	[76]
*	Zn(NO3)2·6H2O	DiP-BDC; DABCO	DMF	–	120	48	–	C2/m	Monoclinic	[76]
*	Zn(NO3)2·6H2O	DB-BDC; DABCO	DMF	–	120	48	–	P4/mmm	Tetragonal	[76]
*	Zn(NO3)2·6H2O	DPe-BDC; DABCO	DMF	–	120	48	–	I4/mcm	Tetragonal	[76]
*	Zn(NO3)2·6H2O	BA-BDC; DABCO	DMF	–	120	48	–	P4/mmm	Tetragonal	[76]
*	Zn(NO3)2·6H2O	BPy-BDC; DABCO	DMF	–	120	48	–	P4/mmm	Tetragonal	[76]
CID-23	Zn(NO3)2·6H2O	BPA; IP	DMF	–	120	48	5.6 × 8.6	$P\overline{1}$	triclinic	[77]
FMOF-1	AgNO3	NaTz	MeOH	–	rt	n/a	12.2 × 7.3; 4.9 × 6.6	$I\overline{4}2d$	Tetragonal	[78,79]
*	Zn(OAc)2·2H2O	H3PBC; 2,2’-bpy	DMF	–	170	96	4.1 × 4.1; 2.7 × 2.7	C2/c	Monoclinic	[80]
UCY-3	Cd(NO3)2 4H2O	H3CIP	DMF	–	100	20	5–7	C2/c	Monoclinic	[81]
FMOF-2	Zn(NO3)2·6H2O	H2hfipbb	DMF; EtOH	–	110	a few hours	–	P2/n	Monoclinic	[82]
SUMOF-6	Ln(NO3)6 salt	H2BPYDC	DMF	–	120	24	19.0 × 5.3	P2/n	Monoclinic	[83]
*	CuCl2·2H2O	H2DMCAPZ	DMF; MeOH	–	90	24	6.7 × 7.2(br)9.7 × 9.6	I41md	Tetragonal	[84]
*	Zn(NO3)2·6H2O	BDC; BTZ; PYZ	DMA; MeOH	–	120	120	13.5 × 8.5	C2m	Monoclinic	[85]
*	Zn(NO3)2·6H2O	BDC; TZ; PYZ	DMF	–	120	120	14.5 × 5.0	$P\overline{1}$	Triclinic	[85]

2,2’-bpy = 2,2’-bipyridine; 2,5-BME-BDC = 2,5-bis(2-methoxyethoxy)-1,4-benzenedicarboxylic acid; 2,3-BME-BDC = 2,3-bis(2-methoxyethoxy)-1,4-benzenedicarboxylic acid; 4,4′-bpy = 4,4′-bipyridine; ADC = Acetylenedicarboxylic acid; BA-BDC = 2,5-Bis(allyloxy)-1,4-benzenedicarboxylic acid; BDC = 1,4-benzene-dicarboxylic acid; BPA = 1,4-bis(4-pyridyl)acetylene; BPNDC = Benzophenone-4,4′-dicarboxylate; BPy-BDC = 2,5-Bis(prop-2-ynyloxy)-1,4-benzenedicarboxylic acid; BTC = 1,3,5-benzene-tricarboxylic acid; BTZ = 1H-benzotriazole; DABCO = 1,4-diazabicyclo-[2.2.2]octane; DB-BDC = 2,5-di-butoxy-1,4-benzenedicarboxylic acid; DE-BDC = 2,5-di-ethoxy-1,4-benzenedicarboxylic acid; DEF = N,N-diethylformamide; DP-BDC = 2,5-di-propoxy-1,4-benzenedicarboxylic acid; DPe-BDC = 2,5-di-pentoxy-1,4-benzenedicarboxylic acid; DiP-BDC = 2,5-di-iso-propoxy-1,4-benzenedicarboxylic acid; DMA = N,N-dimethylacetamide; DMF = N,N-dimethylformamide; EtOH = Ethanol; H₂BDP = 1,4-benzene-dipyrozolate; H₂BPYDC = 2,2’-bipyridine-5,5’-dicarboxylic acid; H₂DMCAPZ = 3,5-Dimethyl-4-Carboxypyrazole; H₂hfipbb = 2,2’-bis(4-carboxyphenyl)hexafluoropropane; H₂PHBPZ = 3,3’,5,5’-tetraphenyl-1H,1’H-4,4′-bipyrazole; H₃CIP = 5-(4-carboxybenzylideneamino)isophthalic acid; H3PBC = 4-phosphono-benzoic acid; H₃BTB = Benzenetribenoic acid or 1,3,5-tris(4-carboxyphenyl)benzene acid; H₄DHTP = 2,5-dihydroxyterephtalic acid; IP = Isophthalic acid; MeOH = Methanol; NaTz = sodium perfluorinated ligand 3,5-bis(trifluoromethyl)-1,2,4-triazolate; PYZ = pyrazine; TCPOM = Tetrakis[4-(carboxyphenyl)oxamethyl]methane; TZ = 1,2,3-1H-triazole

^*haven’t been named.