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. 2016 May 27;9(6):423. doi: 10.3390/ma9060423
a0 specific surface, m2·m−3
A function of time in desorption model
B function of time in desorption model
dp particle size, m
D12 binary diffusion coefficient, m2·s−1
e extraction yield, kg (kg biomass)−1
kf external mass transfer coefficient, m s−1
K partition coefficient, kg biomass (kg CO2)−1
M CO2 in extraction bed, kg
n number of mixers
N biomass feed, kg
p1,2 roots of the desorption model, s−1
P pressure, MPa
q (=qt), solvent-to-feed, kg CO2 (kg biomass)−1
q (=Q’/N), specific flow rate, kg CO2 (kg biomass)−1·s−1
Q flow rate, kg·s−1
R constant in desorption model
Re (=Qdp/(μSE)), Reynolds number
S constant in desorption model
SE cross section of extractor, m2
Sc (=μ/(D12ρf), Schmidt number
Sh (kfdp/D12), Sherwood number
t time, s
tc (=tf + ti), characteristic mass transfer resistance time, s
tf (=ε/(kfa0)), external mass transfer resistance, s
ti mass transfer resistance in particle pores, s
tr (=M/Q’), residence time, s
T temperature, °C
T1 estimate of time constant in desorption model, s
V volume of extraction bed, m3
x solid phase concentration, kg (kg biomass)−1
xt transition solid phase concentration, kg (kg biomass)−1
xu (=x0 + γ y0), content of extractable lipids in biomass, kg (kg biomass)−1
y fluid phase concentration, kg (kg CO2)−1
ys solubility, kg (kg CO2)−1
z dimensionless axial co-ordinate
Greek letters
γ (=M/N = qtr), CO2 in extraction bed-to-feed ratio, kg kg−1
ε void fraction
μ viscosity, kg·m−1·s−1
ρf CO2 density, kg·m−3
ρs density of particles, kg·m−3
Subscripts
asymptotic value
+ equilibrium
0-Jan-1900 initial value
1-Jan-1900 end of extraction of free solute
2-Jan-1900 start of desorption
a,b two sets of adjusted model parameters
j order of mixer