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Time-dependent Kb emission spectra of [Fe(bpy)2(CN)2] in methanol fit with two different kinetic models.
| Kinetic model | Lifetime | Lifetime | Time zero | Instrument response (fs) | |
|---|---|---|---|---|---|
| 1/k1 (fs) | 1/k2 (fs) | t0 (fs) | σ (fs) | Fwhm (fs) | |
| With 3MC intermediate | 120 ± 30 | 60 ± 20 | 0 ± 20 | 80 ± 10 | 180 ± 20 |
| Without 3MC intermediate | 150 ± 40 | 10 ± 15 | 76 ± 10 | 180 ± 20 | |
