Table 1. TONs for the transfer dehydrogenation of COA and TBE catalyzed by 2-H2 a .
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Entry | Catalyst loading (mol%) | T (°C) | t [min] | TON |
1 | 0.3 | 200 | 5 | 47 |
2 | 0.3 | 200 | 10 | 80 |
3 | 0.3 | 200 | 30 | 149 |
4 | 0.3 | 200 | 60 | 213 |
5 | 0.3 | 200 | 120 | 245 |
6 | 0.3 | 200 | 180 | 260 |
7 | 0.15 | 200 | 120 | 285 |
8 | 0.15 | 200 | 240 | 340 |
9 | 0.3 | 150 | 60 | 12 |
10 | 0.3 | 150 | 7200 | 220 |
aTONs were calculated based on conversion of TBE determined by GC analysis. COA (2.33 mmol), TBE (2.33 mmol), 2-H2 (3.42–6.83 μmol).