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aReaction conditions: 1 (0.3 mmol), Pd(OPiv)2 (0.036 mmol), L2 (0.12 mmol), Cu(O2CnPr)2 (0.36 mmol), Ag2CO3 (0.6 mmol), CsOPiv (0.36 mmol), MeCN (1.5 mL), heptane (1.5 mL), and air (1 atm), 130 °C, 15 h.
bIsolated yield.
cPd(OPiv)2 (0.045 mmol).
dPd(OPiv)2 (0.06 mmol). Q = 8-quinolinyl.
