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. Author manuscript; available in PMC: 2017 Dec 5.
Published in final edited form as: Inorg Chem. 2016 Nov 11;55(23):12263–12269. doi: 10.1021/acs.inorgchem.6b01988

Scheme 2. Typical TAML Activator Mechanism for kI Step that Accounts for the pH Profile as in Figure 6a.

Scheme 2

aNumerals at the two-sided arrows 1–4 correspond to the rate constants k1–k4, respectively (eq 5).