Table 1. Physical and Spectroscopic Properties of the Four π-Conjugated Organic Semiconductors and the Semiconducting Polymer Nanoparticles SPN1–4 Formulated from Them.
polymer | λmaxa [nm] | Mn [kDa] | Mw/Mn | SPN | diameter [nm] | PDI | ζ potential [mV] | λmax [nm] | ε [cm–1 g L–1] |
---|---|---|---|---|---|---|---|---|---|
PCPDTBT 1 | 709 | 6 | 1.3 | SPN1 | 145 | 0.2 | –37.8 | 700 | 83 |
INDT-T 2 | 802 | 20 | 4.0 | SPN2 | 159 | 0.25 | –25.6 | 780 | 79 |
INDT-S 3 | 844 | 25 | 3.3 | SPN3 | 120 | 0.23 | –29.8 | 790 | 139 |
INDT-BT 4 | 826 | 40 | 3.0 | SPN4 | 160 | 0.25 | –31.0 | 800 | 253 |
λmax measured in chlorobenzene solution.