Table 2.

Intermolecular Multicomponent Carboamination of Alkynes and Alkenes with PhNNPh^a

	Alkene	R2	% Isolated Yield (6:7)b	1H NMR % Yield (6:7)c
5a		Me	54 (40:60)	n.d.
5b		Et	61 (>99:1)	n.d.
5c		Me	42 (9:91)	63 (15:85)d
5d		Et	51 (>99:1)	70 (71:29)e
5ef		Et	40 (>99:1)	n.d.
5f		Et	0	n.d.

^aLoading of [py₂TiCl₂NPh]₂ and reaction yields with respect to PhNNPh.

^bIsolated as the ketone product after hydrolysis. See SI for details.

^cDetermined by 1H NMR analysis of the crude reaction mixture.

^d96:4 ratio of cis:trans cyclopropane product.

^e74:26 ratio of cis:trans cyclopropane product.

^fReaction run in neat alkene.