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. 2017 Jun 6;409(19):4483–4505. doi: 10.1007/s00216-017-0406-7

Table 2.

A glossary of glycoscience terms used in this tutorial

Monosaccharide nomenclature Glc Glucose
GlcNAc 2-N-acetylglucosamine
Gal Galactose
GalNAc 2-N-acetylgalactosamine
Man Mannose
Fuc Fucose
NeuAc 5-N-acetylneuraminic acid
Sialic acid A general term for neuraminic acids
Hex Hexose (e.g., Glc or Gal or Man)
HexNAc N-acetylhexosamine (e.g., GlcNAc or GalNAc)
dHex Deoxyhexose (e.g., Fuc)
Other terminologies Reducing end The reducing end of a glycan is the monosaccharide with a free anomeric carbon that is not involved in a glycosidic bond and is thus capable of converting to the open ring form
Permethylation Derivatization of all OH to O-methyl and NH to N-methyl
Glycosidic bond Covalent bonds associated with carbohydrates
Cross-ring cleavage Fragmentation across a monosaccharide ring
Scar A nonmethylated hydroxyl group of glycan exposed by tandem MS fragmentation of a glycosidic bond in a permethylated glycan
β-Elimination Release of O-glycosidic linkages between glycans and the β-hydroxyl groups of serine or threonine