Table 1. Summary of measured hygroscopic growth for inorganic sea salt particles and NaCl.
Measurement | Ddry |
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ge(RH=90%) | κs(RH=90%) |
Sea salt (HTDMA, chamber) | 50 nm | — | 2.12 | 1.14 |
Sea salt (HTDMA, chamber) | 100 nm | — | 2.12 | 1.04 |
Sea salt (HTDMA, chamber) | 150 nm | — | 2.09 | 0.96 |
Sea salt (HTDMA, nebulizer) | 50 nm | — | 2.22 | 1.31 |
Sea salt (HTDMA, nebulizer) | 100 nm | — | 2.20 | 1.17 |
Sea salt (HTDMA, nebulizer) | 150 nm | — | 2.19 | 1.12 |
Sea salt (EDB) | ∼7 μm | 5.24 | 2.09 (2.11) | 0.91 (0.95) |
Sea salt (water activity) | Bulk | 5.83 | 2.18 (2.20) | 1.04 (1.08) |
NaCl (HTDMA, nebulizer) | 50 nm | — | 2.26 | 1.39 |
NaCl (HTDMA, nebulizer) | 100 nm | — | 2.29 | 1.34 |
NaCl (HTDMA, nebulizer) | 150 nm | — | 2.29 | 1.30 |
NaCl (EDB) | ∼7 μm | 6.1 | 2.29 | 1.22 |
NaCl (theory) | 50 nm | 6.40 | 2.33 | 1.51 |
NaCl (theory) | 100 nm | 6.73 | 2.38 | 1.49 |
NaCl (theory) | 150 nm | 6.85 | 2.39 | 1.48 |
NaCl (theory) | 7 μm | 7.10 | 2.42 | 1.47 |
Measured hygroscopic growth factors ge(RH), mass growth factors (RH=90%) and corresponding κs values of the inorganic sea salt at RH=90%. The values for ge(RH) of the EDB and the water activity measurements are calculated using the measured dry density of 2.017 g cm−3 and the RH-dependent density parameterization of Tang et al.10 for seawater. The values in parenthesis are calculated assuming that the volume of solutes and water are additive. The theoretical values for NaCl are shown as a reference (taken from ref. 56). The κs values were calculated at RH=90% and room temperature (T=298.15 K) according to Petters and Kreidenweis30 assuming the surface tension of water.