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. 2017 Jun 12;19(13):3612–3615. doi: 10.1021/acs.orglett.7b01588

Scheme 1. Scope of Potassium Alkyltrifluoroborates in Cross-Coupling with Carboxylic Acids.

Scheme 1

See Supporting Information for experimental details. All cited yields are isolated.

Reaction performed on 7.0 mmol scale with 1.5 mol % of Ir photocatalyst 1 and 3.0 mol % of [Ni(dtbbpy)(H2O)4]Cl2.