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. Author manuscript; available in PMC: 2017 Jul 14.

Published in final edited form as: J Org Chem. 2017 Feb 16;82(5):2545–2557. doi: 10.1021/acs.joc.6b02941

Table 2.

Half-wave potentials (V vs. SCE) for BODIPYs 2, 3, 4, 6a, 6b, 7 and 8 in PhCN with 0.1 M TBAP .

	Oxidation (V)		Reduction (V)			H-L (V)
BODIPY	2^nd	1^st	1^st	2^nd	Δ (2–1) (V)	Gap^b
2	2.00^a	1.58	−0.58	−1.62^a	1.04	2.16
3	1.66^a	1.22	−0.72	−1.76^a	1.04	1.94
4	1.86^a	1.34	−0.77	−1.81^a	1.04	2.11
6a	1.69	1.38	−0.57	−1.31	0.74	1.95
6b	1.68	1.38	−0.53	−1.27	0.74	1.91
7	1.62^a	1.15	−0.64	−1.38^a	0.74	1.79
8	1.49	1.22	−0.68	−1.42^a	0.74	1.90

^a

Peak potential, E_p at scan rate of 0.1 V/s;

^b

HOMO - LUMO Gap = |E_1/2 (1^st Ox) − E_1/2 (1^st Red)|.