Table 4. Scope of the benzophenone-catalyzed photochemical aliphatic C–H chlorination.
| ||||
---|---|---|---|---|
Entry | Substrate | Product | Time | Isolated yielda or conversion |
1 | 24 h | 95% | ||
2 | 24 h | 95% | ||
3 | 9 h | 70% | ||
4 | 9 h | 82% | ||
5 | 24 h | 86% conversion | ||
6 | 24 h | 76% conversion |
Calculated based on NCS.
Product distribution determined by 1H NMR.