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. Author manuscript; available in PMC: 2018 Jun 29.
Published in final edited form as: Tetrahedron. 2017 May 4;73(26):3696–3701. doi: 10.1016/j.tet.2017.05.008

Table 4. Scope of the benzophenone-catalyzed photochemical aliphatic C–H chlorination.

graphic file with name nihms874461u5.jpg

Entry Substrate Product Time Isolated yielda or conversion
1 graphic file with name nihms874461t19.jpg graphic file with name nihms874461t20.jpg 24 h 95%
2 graphic file with name nihms874461t21.jpg graphic file with name nihms874461t22.jpg 24 h 95%
3 graphic file with name nihms874461t23.jpg graphic file with name nihms874461t24.jpg 9 h 70%
4 graphic file with name nihms874461t25.jpg graphic file with name nihms874461t26.jpg 9 h 82%
5 graphic file with name nihms874461t27.jpg graphic file with name nihms874461t28.jpg 24 h 86% conversion
6 graphic file with name nihms874461t29.jpg graphic file with name nihms874461t30.jpg 24 h 76% conversion
a

Calculated based on NCS.

b

Product distribution determined by 1H NMR.