Figure 14.
Solvent effect on the ionic liquid electrolyte from all‐atom classical MD simulations: (a) differential capacitance of a dicationic ionic liquid on the graphite basal plane with added solvents (acetonitrile, ACN; propylene carbonate, PC) in 5% molar ratio: [C6(mim)2](Tf2N)2 = 1‐hexyl‐3‐dimethylimidazolium bis[(trifluoromethyl)sulfonyl]imide; Reproduced with permission.171 Copyright 2014, IOP Publishing. (b) cation diffusivity in 1‐butyl‐3‐methyl‐imidazolium bis[(trifluoromethyl)sulfonyl]imide, [BMIM+][Tf2N−], in solvents of different dipole moments at 50 wt%. Reproduced with permission.173 Copyright 2017, American Chemical Society.