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. 2017 May 29;4(7):1700107. doi: 10.1002/advs.201700107

Table 1.

Performance of paper‐supported electrodes in flexible energy storage devices

Electrodes Synthesis method Device Performance Ref.
Capacitance/Capacity Power Density Energy Density Cycling Stability
PPy‐paper Soaking and polymerization SC* 1.5 F cm−2 0.46 W cm−3 1 mWh cm−3 75.6% after 10000 cycles 12
370 F g−1
PPy‐bacterial cellulose paper Vacuum filtration SC 2.43 F cm−2 94.5% after 5000 cycles 74
PPy‐cladophora cellulose paper Vacuum filtration SC 315 C g−1 2.7 kW kg−1 1.75 Wh kg−1 No loss after 1500 cycles 72
PANI‐paper Electrodeposition SC 160 F g−1 81% after 1000 cycles 55
PANI‐graphite‐Paper Pencil‐drawing Electrodeposition SC 355.6 mF cm−2 0.054 W cm−3 0.32 mWh cm−3 83% after 10000 cycles 14
PANI‐nylon‐cellulose acetate‐paper Electrospinning Electrodeposition SC 402 F g−1 61% after 1000 cycles 93
PEDOT‐paper In situ Polymerization SC 145 F cm−3 1 W cm−3 1 mWh cm−3 91% after 2500 cycles 56
115 F g−1
PEDOT‐paper Spin coating SC 994 μF cm−2 * 64.70 W cm−3 1.77 mWh cm−3 No loss after 12000 cycles 94
16.6 F cm−3 *
CNT‐paper Dip and dry SC 115.83 F g−1 48.86 Wh kg−1 57
CNT‐paper Mayer rod printing SC 200 F g−1 * 200 kW kg−1 47 Wh kg−1 97% after 40000 cycles 47
CNT‐PVDF‐paper printing SC 33 F g−1 250 kW kg−1 96.9% after 2500 cycles 64
MnO2‐CNT‐paper Dip and dry SC 1162 F g−1 4 mW cm−2 4.2 µWh cm−2 97.8% after 20000 cycles 95
Si‐CNT‐paper Vacuum filtration PECVD* LIB* 2100 mAh g−1 77% after 100 cycles 96
PEDOT‐CNT‐paper Ink‐jet printing SC 23.6 F cm−3 89.1 mW cm−3 42 mWh cm−3 92% after 10000 cycles 97
h‐MnO2‐CNT‐paper Printing SC 1035 F g−1 81 kW kg−1 25.3 Wh kg−1 98.9% after 10000 cycles 98
91.7 mF cm−2
CNT‐MnO2‐CNT‐paper Dip‐and‐dry electrodeposition SC 327 F g−1 85% after 50000 cycles 99
LiMn2O4‐CNT‐paper Mayer rods printing Pressing LIB 110 mAh g−1 93% after 50 cycles 30
Li4Ti5O12‐CNT‐paper LIB 149 mAh g−1 96% after 50 cycles
Graphene‐paper Vacuum filtration SC 252 F g−1 2.4 kW kg−1 237 Wh kg−1 59
LIB 540 mAh g−1 22.9% after 45 cycles 75
Graphite‐paper Pencil‐drawing SC 2.3 mF cm−2 35 kW kg−1 1.46 Wh kg−1 90% after 15000 cycles 48
Graphite‐paper Vacuum filtration LIB 350 mAh g−1 94.5% after 120 cycles 58
MnO2‐Ni‐paper Electroless plating Electrodeposition SC 1.9 F cm−2 2.5 mW cm−2 0.8 mWh cm−3 85.1% after 1000 cycles 100
MnO2‐Ni‐graphite‐paper Pencil‐drawing Electrodeposition SC 175 mF cm−2 48 mW cm−3 106 mWh cm−3 96% after 6000 cycles 62
60 kW kg−1 66.2 Wh kg−1
Mn3O4‐Ni‐graphite‐paper Pencil‐drawing Electrodeposition SC 432 mF cm−2 33 mW cm−3 0.35 mWh cm−3 83% after 12000 cycles 63
432 F g−1
Co2NiO4‐Ni‐graphite‐paper Pencil‐drawing Electrodeposition SC 734 mF cm−2 0.79 W cm−3 2.48 mWh cm−3 97.6% after 15000 cycles 61
25.6 kW kg−1 80 Wh kg−1
PANI‐Au‐paper Evaporation and Electrodeposition SC 560 F g−1 3 W cm−3 0.01 Wh cm−3 103% after 10000 cycles 32
0.8 F cm−2
Si‐CNTs‐CNC film Vacuum filtration LIB 3200 mAh g−1 57.5% after 100 cycles 101

*Notes: Supercapacitor (SC), Lithium‐ion batteries (LIB), Plasma‐enhanced chemical vapor deposition (PECVD).